UCSB Hazardous Materials Disclosure

To: Campus Purchasing Staff

Re: UCSB Hazardous Materials Disclosure, Annual reminder

As outlined below, Santa Barbara County Fire, the U.S. Department of Homeland Security and the U.S. Drug Enforcement Agency have special regulatory requirements for certain hazardous materials and dangerous drugs that might come onto campus. Please contact me as soon as possible if any of the materials listed below will be ordered:

  1. Any material equal to or greater than the following:

    • 55 gallons of a liquid (very rare), or
    • 500 pounds of a solid (very rare), or
    • Compressed gases: new orders (not replacements) of large sized cylinders Greater than 36 inches of Ammonia, Hydrogen, Oxygen, Methane, or other hazardous gases.
    Image
    Gas cylinder height and volume chart. Displays cylinders ranging from 18 inches (22 cubic feet) to 60 inches (330 cubic feet). Highlighting cylinders greater than 36 inches in height (80, 122, 250, and 330 cubic feet) as requiring disclosure.
    Figure 1: Gas cylinder height comparisons (inches) and cubic foot capacities. New orders of cylinders greater than 36 inches require advance disclosure.

    I DO NOT need to be contacted for these non-hazardous gases: Compressed air, Argon, Carbon dioxide, Helium, Krypton, Neon, Nitrogen, and Xenon or combination mixture of these.

  2. Controlled substances (i.e., DEA listed drugs) and materials that can be converted to drugs (DEA listed precursors) are highly regulated. Principal Investigators must have a DEA registration to order controlled substances. Additionally there are special requirements to order other materials such as drug precursors. For questions regarding controlled substances or drug precursors contact Derek Iverson at x3743, or Derek.Iverson@ehs.ucsb.edu

  3. Please contact me immediately if any of the Chemical of Interest listed below (alphabetized) are to be ordered in any quantity. Specific safety requirements or reporting may be necessary:

    Alphabetical List of Chemicals of Interest and CAS Numbers
    Chemical of InterestCAS Number
    1,3-Bis(2-chloroethylthio)-n-propane63905-10-2
    1,3-butadiene106-99-0
    1,4-Bis(2-chloroethylthio)-n-butane142868-93-7
    1,5-Bis(2-chloroethylthio)-n-pentane142868-94-8
    2-acetylaminofluorene53-96-3
    2-Chloroethylchloro-methylsulfide2625-76-5
    3,3-dichlorobenzidine (& its salts)91-94-1
    4,4'-methylenebis(2-choroaniline)101-14-4
    4-aminodiphenyl92-67-1
    4-dimethylaminoazobenzene60-11-7
    4-nitrobiphenyl92-93-3
    Acetyl peroxide 
    Acrylonitrile107-13-1
    alpha-Napthylamine134-32-7
    Aluminum (powder)7429-90-5
    Aluminum alkyls 
    Ammonium perchlorate (particle size >15 microns) 
    Ammonium permanganate 
    Arsenic (& its compounds)CAS VARY
    Arsenic trichloride [Arsenous trichloride] 
    Arsine7784-42-1
    Benzene71-43-2
    Benzidine (and its salts):92-87-5
    beta-Napthylamine91-59-8
    beta-Propiolactone57-57-8
    Bis(2-chloroethylthio) methane63869-13-6
    Bis(2-chloroethylthiomethyl)ether63918-90-1
    bis-Chloromethylether542-88-1
    Boron tribromide10294-33-4
    Boron trifluoride (gas)7637-07-2
    Bromine chloride (gas)13863-41-7
    Bromine pentafluoride 
    Bromine trifluoride (gas)7787-71-5
    Cadmium (& its compounds)CAS VARY
    Carbonyl fluoride (gas)353-50-4
    Chlorine7782-50-5
    Chlorine pentafluoride13637-63-3
    Chlorine trifluoride (gas)7790-91-2
    Chlorosarin1445-76-7
    Chlorosoman7040-57-5
    Chromic chloride 
    Chromium (VI) e.g., salts of dichromate, chromate. Chromium trioxide, ...)7440-47-3
    Cyanogen460-19-5
    Cyanogen chloride (gas)506-77-4
    DF (Methyl phosphonyl difluoride)676-99-3
    Di- or Trinitrobenzene 
    Diborane19287-45-7
    Dibromochloropropane96-12-8
    Dibutyl peroxide2524-01-8
    Dichloromethane75-09-2
    Dichlorosilane (gas)4109-96-0
    Diethyl aluminum chloride96-10-6
    Diethyl beryllium542-63-2
    Diethyl methylphosphonite15715-41-0
    Diethyl phosphine627-49-6
    Dinitrogen tetroxide (gas)10544-72-6
    Emetin dihydrochloride 
    Ethyl nitrate109-95-5
    Ethyl phosphonyl difluoride753-98-0
    Ethylene dibromide 
    Ethylene oxide75-21-8
    Ethyleneimine151-56-4
    Ethylphosphonothioic dichloride993-43-1
    Fluorine7782-41-4
    Formaldehyde50-00-0
    Germane994-65-0
    Germanium tetrafluoride (gas)7783-58-6
    Guanidine nitrate506-93-4
    Hexafluoroacetone (gas)684-16-2
    HN1 (nitrogen mustard-1)538-07-8
    HN2 (nitrogen mustard-2)51-75-2
    HN3 (nitrogen mustard-3)555-77-1
    Hydrogen cyanide74-90-8
    Hydrogen fluoride7664-39-3
    Hydrogen peroxide solutions (>52% conc.)7722-84-1
    Hydrogen selenide7783-07-5
    Hydrogen sulfide7783-06-4
    Hydroxylamine 
    Inorganic lead compounds: 
    Isopropylphosphonothioic dichloride1498-60-8
    Isopropylphosphonyl difluoride677-42-9
    Lewisite 1 [2-Chlorovinyldichloroarsine]541-25-3
    Lewisite 2 [Bis(2-chlorovinyl) chloroarsine]40334-69-8
    Lewisite 3 [Tris(2-chlorovinyl)arsine]40334-70-1
    Magnesium (powder)7439-95-4
    Methyl bromide74-83-9
    Methyl chloromethylether107-30-2
    Methyl mercaptan74-93-1
    Methylchlorosilane993-00-0
    Methylenedianiline101-77-9
    Methylphosphonothioic dichloride676-98-2
    N,N-(2diethylamino-)ethanethiol100-38-9
    N,N-(2diisopropylamino-) ethanethiol5842-07-9
    N,N-(2dimethylamino-)ethanethiol108-02-1
    N,N-(2dipropylamino-) ethanethiol5842-06-8
    N,N-Diethyl phosphoramidic dichloride1498-54-0
    N,N-Diisopropyl phosphoramidic dichloride23306-80-1
    N,N-Dimethyl phosphoramidic dichloride677-43-0
    N,N-Dipropyl phosphoramidic dichloride40881-98-9
    Nickel carbonyl 
    Nitric acid >68%697-37-2
    Nitric oxide10102-43-9
    Nitrogen dioxide10102-44-0
    Nitrogen mustard hydrochloride55-86-7
    Nitrogen trioxide (gas)10544-73-7
    Nitromethane 
    Nitrosyl chloride (gas)2696-92-6
    N-Nitrosodimethylamine62-75-9
    o,o-Diethyl S-[2-(diethylamino) ethyl] phosphorothiolate78-53-5
    O-Mustard (T)63918-89-8
    Organic azides 
    Oxygen difluoride (gas)7783-41-7
    Ozone10028-15-6
    Perchloric acid (> 52% by wt.)7601-90-3
    Perchloryl fluoride (gas)7616-94-6
    Peroxyacetic acid 
    Phosgene75-44-5
    Phosphine7803-51-2
    Phosphorus trichloride7719-12-2
    Picric acid (dry)88-89-1
    Potassium Metal 
    Propylphosphonothioic dichloride2524-01-8
    Propylphosphonyl difluoride690-14-2
    QL [o-Ethyl-o-2-diisopropylaminoethyl methyl phosphonite]57856-11-8
    Sarin [o-Isopropyl methylphosphonofluoridate]107-44-8
    Selenium hexafluoride (gas)7783-79-1
    Sesquimustard3563-36-8
    Silane7803-62-5
    Silicon tetrafluoride (gas)7783-61-1
    Sodium metal 
    Soman96-64-0
    Stibine (gas)7803-52-3
    Sulfur mustard (Mustard gas (H))505-60-2
    Sulfur tetrafluoride753-98-0
    Tabun77-81-6
    t-butyl lithium 
    Tellurium hexafluoride (gas)7783-80-4
    Thiodiglycol [Bis(2-hydroxyethyl)sulfide]111-48-8
    Titanium tetrachloride7550-45-0
    Triethyl aluminum etherate 
    Triethyl bismuthine593-91-9
    Triethyl boron 
    Trifluoroacetyl chloride (gas)354-32-5
    Trimethyl gallium 
    Trimethylaluminum 
    Tungsten hexafluoride (gas)7783-82-6
    VX [o-Ethyl-S-2-diisopropylaminoethyl methylphosphonothiolate]50782-69-9

Your attention to this is greatly appreciated. Please contact me if you have any questions, at X8243 or hector.acuna@ehs.ucsb.edu

Revised 1/2019